Crystal structure of 1-(2',6'-dichlorophenyl)-1-hydroxy-2-o-toluylethane- 2-one, C15H12CI2O2
نویسندگان
چکیده
منابع مشابه
Crystal structure of (-)-(1'R)-1-(2'-hydroxy-1'-phenyl-ethyl)-1H-pyridin-2-one.
wide interest because the 1H-pyridin-2-ones obtained in this process are versatile synthetic building blocks in the synthesis of alkaloids.1–5 The title compound, (–)-(1′R)-1-(2′-hydroxy-1′-phenyl-ethyl)1H-pyridin-2-one II, was prepared by stirring a solution of pyridinium salt, I (4.0 mmol), in water (25 ml) and cooled to 5 ̊C (Scheme 1). A solution of K3Fe(CN)6 (11 eq.) in water (30 ml) was ad...
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In the polymeric title compound, [Cd(C7H4O6S)(C11H6N2O)(H2O)2] n , the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hy-droxy-5-sulfonato-benzoate (Hssal(2-)) ligands and by two N atoms from a 4,5-di-aza-fluoren-9-one (Dafo) ligand in a distorted penta-gonal-bipyramidal geometry. The Cd(2+) atoms are monodentately coordinated by the sulfonate group of one Hs...
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In the title indolinone derivative, C10H10INO, all the non-H atoms, except the terminal methyl C atom, are almost coplanar. The mol-ecules are arranged into columns extending along the a-axis direction and inter-act with the mol-ecules in adjacent columns via C-H⋯O hydrogen bonds [H⋯O distance = 2.57 (3) Å] and I⋯I short contacts of 3.8986 (3) Å. A one-dimensional zigzag iodine chain along the ...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 1999
ISSN: 2197-4578,1433-7266
DOI: 10.1515/ncrs-1999-0443